VANADIUM BASIS SETS FOR THE CRYSTAL PROGRAM
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TCM CRYSTAL basis set library: https://vallico.net/mike_towler/crystal.html

Title:    vanadium 
Author:   N.M. Harrison, V.R.Saunders
When:     1992, modified June 1993
Comments: Basis for isolated V2+ ion
Use:      VO VO2 VMg3O4 (valence modifications reported below) - Ref. 1
          V2O3 - Ref.2 
Refs:     (1) WC Mackrodt et al., Phil Mag A 68, 653 (1993) - VO
          (2) M Catti et al, PRB 55 p.16122 (1997) 

23 7
0 0 8 2.0 1.0
 246297.0     0.000228
  35328.3     0.001929
   7524.86    0.0111
   1969.96    0.0500
    594.016   0.1699
    205.385   0.3687
     80.1571  0.4038
     33.218   0.1440
0 1 6 8.0 1.0
    611.206  -0.0058  0.0086
    146.715  -0.0675  0.0607
     48.724  -0.1278  0.2123
     19.2296  0.2508  0.3966
      8.1086  0.6301  0.4076
      2.8353  0.2781  0.217
0 1 4 8.0 1.0
     31.5966  0.0175 -0.0274
     12.7943 -0.2515 -0.0928
      5.1332 -0.9153  0.2146
      2.2534  0.9818  1.5909
0 1 1 0.0 1.0
      0.9655  1.0     1.0
0 1 1 0.0 1.0
      0.4096  1.0     1.0
0 3 3 3.0 1.0
      16.79   0.05975
      4.372   0.26822
      1.326   0.51315
0 3 1 0.0 1.0
      0.3838  0.45636

modifications for VMg3O4:
Outer sp
 0.973 and 0.3849
d4
0 3 4 3.0 1.0
     15.3252  0.0931
      4.0011  0.3900
      1.2089  0.6859
      0.3519  0.5855

VO (ferromagnetic) d41
Outer sp 
 0.9555 and 0.3812 
d41
0 3 4 3.0 1.0    
     17.532   0.0688 
      4.7623  0.2941 
      1.576   0.5441 
      0.5767  0.5132 
0 3 1 0.0 1.0    
      0.1962  1.0    

VO (ferromagnetic) d31
sp 
 0.8985, 0.3729
d31
0 3 3 3.0 1.0
     11.36    0.0813
      2.996   0.2863
      0.9235  0.4107
0 3 1 0.0 1.0
      0.2907  1.0

VO2 (ferromagnetic) d31
sp (outer only opt) 
 0.3752